物理化学
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刘翔宇

发布日期:2021-02-04  点击量:

 

 

1.个人简历:

1) 工作经历:

201805-201905月,University of Valencia CSC访问学者

200807-至今, 宁夏大学化学化工学院 副教授

2) 学习经历:

201209-201506月,西北大学化学与材料科学学院 材料化学 博士

200509-200807月,宁夏大学化学化工学院 物理化学 硕士

200009-200407月,宁夏大学化学化工学院 化学工程与工艺 学士

主要研究方向包括:1)分子基磁性材料的构筑、表征及应用;2)高能密度材料的制备及理化性能研究;3)多孔金属有机框架材料(MOFs)的合成及气体吸附性能研究。


2. 主要研究方向及成果:

Coordin. Chem. Rev.Green Chem.Chem. Commun.Chem. Eur. J.Inorg. Chem.J. Phys. Chem. CJ. Mater. Chem. ADalton TransactionsNew J. Chem. 等主流源期刊发表SCI论文71(通讯或第一作者37篇,3篇论文入选ESI3%高被引论文,论文他引1100次,H因子19),在《化学教育》等期刊发表教改论文2篇。目前主持在研、完成国家自然科学基金项目2项、宁夏自然科学基金重点项目1项、宁夏高等学校优秀青年培育项目1项、配位化学国家重点实验室开放课题1项、省部共建国家重点实验室开放课题1项、宁夏大学一流学科建设项目1项、主持及参与完成宁夏自然科学基金项目2项、宁夏高等学校科学研究项目1项、宁夏大学科学研究项目2项,主持区级教改项目1项,指导国家级、自治区级大学生创新实验项目5项。主编出版学术著作1部、授权发明专利1项。2019年,指导研究生获得宁夏回族自治区优秀硕士学位论文;2019年,荣获宁夏优秀自然科学论文一等奖1项,2017年,荣获宁夏优秀自然科学论文二等奖、三等奖各1项。2018年,入选第三批“宁夏青年科技人才托举工程”人选。


发表论文(第一或通讯作者)

1. Senni Cao, Xiufang Ma, Xiaohui Ma, Peipei Cen, Yuewei Wu, Jinhui Yang, Xiangyu Liu,* Gang Xie, Sanping Chen. Modulating energetic performance through decorating nitrogen-rich ligands in high-energy MOFs. Dalton Trans., 2020, 49, 2300-2307.

2. Lijuan Duan, Chengcheng Zhang, Peipei Cen, Xiaoyong Jin, Chen Liang, Jinhui Yang, Xiangyu Liu.* Stable Ln-MOFs as multi-responsive photoluminescence sensors for the sensitive sensing of Fe3+, Cr2O72−, and nitrofuran. CrystEngComm, 2020, 22, 1695-1704. (封面文章)

3. Yuewei Wu, Jing Xi, Jinhui Yang, Weiming Song, Shuchang Luo, Zheng Wang, Xiangyu Liu.* Coligand effects on the architectures and magnetic properties of octahedral cobalt(II) complexes with easy-axis magnetic anisotropy. CrystEngComm. 2020, 22, 2297-2303. (Hot Paper)

4. Peipei Cen, Xinagyu Liu,* Yi-Quan Zhang, J Ferrando-Soria, Gang Xie, Sanping Chen, E Pardo. Modulating magnetic dynamics through tailoring the terminal ligands in Dy2 single-molecule magnets. Dalton Trans., 2020, 49, 808–816.

5. Xiufang Ma, Bingbing Chen, Yiquan Zhang, Jinhui Yang, Quan Shi, Yulong Ma, Xiangyu Liu.* Enhancing single-molecule magnet behaviour through decorating terminal ligands in Dy2 compounds. Dalton Trans., 2019, 48, 12622-12631.

6. Xiangyu Liu,* Xiufang Ma, Jinhui Yang, Shuchang Luo, Zheng Wang, Jesús Ferrando-Soria, Yulong Ma, Quan Shi, and Emilio Pardo. Solvent-induced single-crystal-to-single-crystal transformation and tunable magnetic property of 1D azido-Cu (II) chains with carboxylate bridge. Dalton Trans., 2019, 48, 11268–11277.

7. Xiaohui Ma, Chao Cai, Wujuan Sun, Weiming Song, Yulong Ma, Xiangyu Liu,* Gang Xie, Sanping Chen, Shengli Gao. Enhancing energetic performance of multinuclear Ag (I)-cluster MOF-based high-energy-density materials by thermal dehydration. ACS Appl. Mater. Interfaces, 2019, 11, 9233−9238.

8. Yuewei Wu, Danian Tian, Jesús Ferrando-Soria, Joan Cano, Lei Yin, Zhongwen Ouyang, Zhenxing Wang, Shuchang Luo, Xiangyu Liu,* Emilio Pardo. Modulation of the magnetic anisotropy of octahedral cobalt(II) single-ion magnets by fine-tuning the axial coordination microenvironment. Inorg. Chem. Front., 2019, 6, 848-856.

9. Fengqin An, Chengcheng Zhang, Lijuan Duan, Xiangyu Liu*, Zheng Wang, Xiaoyong Jin, Weiming Song. Luminescent metal–organic frameworks with a 2-(4-pyridyl)-terephthalic acid ligand for detection of acetone. New J. Chem., 2019, 43, 4800-4807.

10. Peipei Cen, Xiangyu Liu,* Jesús Ferrando-Soria, Yi-Quan Zhang, Gang Xie, Sanping Chen,* Emilio Pardo. Capping N-Donor Ligands Modulate the Magnetic Dynamics of β-Diketonate-DyIII Single-Ion Magnets with D4d Symmetry. Chemistry–A European Journal, 2019, 25, 3884-3892.

11. Peipei Cen, Weize Yuan, Mengyao Tan, Bingbing Chen, Weiming Song, Zheng Wang, Xiangyu Liu*. Field-induced slow magnetic relaxation in an octahedral high-spin Co(II) complex. Inorganic Chemistry Communications. 2019, 99, 195-198.

12. Xiangyu Liu,* Xiufang Ma, Weize Yue, Peipei Cen, Yi-Quan Zhang. Jesus. Ferrando-Soria, Sanping Chen, Emilio Pardo. Concise Chemistry Modulation of the SMM Behavior within a Family of Mononuclear Dy(III) Complexes. Inorg. Chem., 2018, 57, 14843-14851.

13. Xiaohui Ma, Yaru Liu, Weiming Song, Zheng Wang, Xiangyu Liu,* Gang Xie, Sanping Chen, Shengli Gao. A difunctional azido-cobalt(ii) coordination polymer exhibiting slow magnetic relaxation behaviour and high-energy characteristics with good thermostability and insensitivity. Dalton Transactions, 2018, 47, 12092-12104.

14. Xiangyu Liu,* Xiufang Ma, Peipei Cen, Fengqing An, Zheng Wang, Weiming Song, Yi-Quan Zhang.* One-dimensional cobalt(II) coordination polymer featuring single-ion-magnet-type field-induced slow magnetic relaxation. New Journal of Chemistry, 2018, 42, 9612-9619.

15. Zhao Xu, Fengqin An, Xiaohui Ma, Huiliang Zhou, Weiming Song, Xiangyu Liu.* Lanthanide(III) complex metal-organic frameworks with a phenanthroline-carboxylate derivate and 2,5-thiophenedicarboxylate coligand: hydrothermal synthesis, crystal structure, and high thermostability. Zeitschrift für Naturforschung B, 2018, 73(5), 311-317.

16. Haiwen Wei, Qingfeng Yang*, Xiaoyong Lai, Xiaozhong Wang, Tianlin Yang, Qin Hou, Xiangyu Liu*. Field-Induced Slow Relaxation of the Magnetization in a Distorted Octahedral Mononuclear High-Spin Co(II) Complex. CrystEngComm, 2018,20(7), 962-968.

17. Xiaohui Ma, Yuewei Wu, Peipei Cen, Shenru Ma, Chengcheng Zhang, Shuchang Luo, Huiliang Zhou, Weiming Song, Xiangyu Liu.* Ferromagnetic ordering and slow magnetic relaxation observed in a triple-bridged azido-Cu(II) chain compound with mixed carboxylate/ethanol linkers. New Journal of Chemistry, 2017, 41, 9631-9638.

18. Xiangyu Liu,* Xiaohui Ma, Peipei Cen, Yuewei Wu, Chengcheng Zhang, Quan Shi,* Weiming Song, Gang Xie, Sanping Chen. A Substituent effect of phenylacetic acid coligands perturbed structures and magnetic properties observed in two triple-bridged azido-Cu (II) chain compounds with ferromagnetic ordering and slow magnetic relaxation. Dalton Transactions, 2017, 46, 7556-7566.

19. Xiangyu Liu,* Pei-Pei Cen, Li-Zhou Wu, Feifei Li, Wei-Ming Song, Gang Xie, San-Ping Chen*. Tuning of Exchange Coupling and Switchable Magnetization Dynamics by Displacing the Bridging Ligands Observed in Two Dimeric Manganese (III) Compounds. Scientific Reports, 2017, 2017, 7, 44982-44990.

20. Pei-Pei Cen, Sheng Zhang, Xiangyu Liu,* Wei-Ming Song, Yi-Quan Zhang,* Gang Xie, San-Ping Chen*. Electrostatic Potential Determined Magnetic Dynamics Observed in Two Mononuclear β‑Diketone Dysprosium(III) Single-Molecule Magnets. Inorg. Chem., 2017, 56, 3644-3656.

21. Xiangyu Liu,* Feifei Li, Xiaohui Ma, Peipei Cen, Shuchang Luo, Quan Shi, Shenru Ma, Yuewei Wu, Chengcheng Zhang, Zhao Xu, Weiming Song, Gang Xie, Sanping Chen. Coligand modifications fine-tuned the structure and magnetic properties of two triple-bridged azido-Cu(II) chain compounds exhibiting ferromagnetic ordering and slow relaxation. Dalton Transactions, 2017, 46, 1207–1217.

22. Yuewei Wu, Chengcheng Zhang, Zhao Xu, Chao Cai, Weiming Song, Xiaoying Zhang, Yangyang Tian, Xiangyu Liu*. Two new cobalt-organic frameworks constructed from polycarboxylates and pyridine-triazole ligands: Synthesis, crystal structures and magnetic properties. Inorg. Chem. Commun., 2017, 84, 190-194.

23. Xiaohui Ma, Feifei Li, Peipei Cen, Xiangyu Liu,* Huiliang Zhou, Shuchang Luo, Yuewei Wu, Chengcheng Zhang, Weiming Song. One-dimensional Cu(II) chain compound with simultaneous EO-azido and carboxylato bridges displaying strong ferromagnetic coupling: synthesis, crystal structure, magnetic properties with DFT calculations. Chinese journal of inorganic chemistry. 2017, 33, 1639-1648.

24. Xiangyu Liu*, Peipei Cen, Feifei Li, Xiaohui Ma, Huiliang Zhou, Xiaoyan Chen, Weiming Song, Gang Xie, Sanping Chen. A unusual two-dimensional azido-Cu(II) network with benzoate derivative as coligand exhibiting ferromagnetic order and slow magnetic relaxation. RSC Adv, 2016, 6, 96103-96108.

25. Xiangyu Liu*, Huaixian Liu, Peipei Cen, Xiaoyan Chen, Huiliang Zhou, Weiming Song, Qilin Hu . Auxiliary ligand-triggered assembly of two dinuclear Cu(II) compounds with a pyridylhydrazone derivative: Synthesis, crystal structure and magnetic property. Inorg. Chim. Acta, 2016, 447, 12-17.

26. Xiangyu Liu*, Lin Sun, Huiliang Zhou, Peipei Cen, Xiaoyong Jin, Gang Xie, Sanping Chen, Qilin Hu. Single-Ion-Magnet Behavior in a Two-Dimensional Coordination Polymer Constructed from CoII Nodes and a Pyridylhydrazone Derivative. Inorg. Chem., 2015, 54, 8884–8886.

27. Xiangyu liu, Wenjuan Gao, Panpan Sun, Zhiyong Su, Sanping Chen,* Qing Wei, Gang Xie, Shengli Gao. Environmentally-friendly high-energy MOFs: crystal structure, thermostability, insensitivity and remarkable detonation performance. Green Chem., 2015, 17, 831-836.

28. Xiangyu Liu, Xiaoni Qu, Sheng Zhang, Hongshan Ke, Qi Yang, Quan Shi, Qing Wei, Gang Xie, Sanping Chen*. High-Performance Energetic Characteristics and Magnetic Properties of a Three-Dimensional Cobalt (II) Metal–Organic Framework Assembled with Azido and Triazole. Inorg. Chem., 2015, 54(23), 11520–11525.

29. Xiangyu Liu*, Peipei Cen, Huiliang Zhou, Xiaoyong Jin, Qilin Hu, Yongqiang Ji. A new 3D Cd(II) metal–organic framework with discrete (H2O)6clusters based onflexible cyclohexane-1,2,4,5-tetracarboxylic acid ligand. Inorg. Chem. Commun., 2015, 53, 11–14.

30. Lin Sun, Huaixian Liu, Huiliang Zhou, Xiangyu Liu*, Weiming Song, Bing Li, Qilin Hu. A Cobalt(II) Coordination Compound with 1H-3-(3-pyridyl)-5-(3′-pyridyl)-1,2,4-triazole: Synthesis, Crystal Structure, Thermostability and DFT Calculation of Ligand. Chinese journal of inorganic chemistry. 2015, 31, 1207-1214.

31. Xiangyu Liu*, Huaixian Liu, Huiliang Zhou, Peipei Cen, Xiaoyong Jin, Weiming Song, Shuchang Luo, Qilin Hu. A new cobalt(II)-containing coordination polymer composed of dinuclear metal units: synthesis, crystal structure and magnetic property with DFT calculation. Canadian Journal of Chemistry, 2015, 93(11), 1214-1218.

32. Huaixian Liu, Lin Sun, Huiliang Zhou, Peipei Cen, Xiaoyong Jin, Xiangyu Liu*, Qilin Hu. A mononuclear cobalt(III) 3-(2-pyridyl)-5-phenyl-1,2,4-triazolato complex: hydrothermal synthesis, crystal structure, thermostability, and DFT calculations. Zeitschrift fur naturforschung section b, 2015, 70(9), 631-636.

33. Xiangyu Liu, Peipei Cen, Hui Li, Hongshan Ke, Sheng Zhang,Qing Wei, Gang Xie, Sanping Chen,* Shengli Gao. Solvent-Induced Syntheses, Crystal Structures, Magnetic Properties and Single-Crystal-to-Single-Crystal Transformation of Azido-Cu(II) Coordination Polymers with 2-Naphthoic Acid as Coligand. Inorg. Chem., 2014, 53 (15), 8088–8097.

34. Xiangyu Liu, Zhiyong Su, Wenxin Ji, Sanping Chen,* Qing Wei, Gang Xie, Xuwu Yang, Shengli Gao. Structure, Physicochemical Properties, and Density Functional Theory Calculation of High-Energy-Density Materials Constructed with Intermolecular Interaction: Nitro Group Charge Determines Sensitivity. J. Phys. Chem. C, 2014, 118, 23487−23498.

35. Xiangyu Liu, Sanping Chen,* Thais Grancha, Emilio Pardo,* Hongshan Ke, Bing Yin, Qing Wei, Gang Xie, Shengli Gao. A triple-bridged azido-Cu(II) chain compound fine-tuned by mixed carboxylate/ethanol linkers displays slow-relaxation and ferromagnetic order: synthesis, crystal structure, magnetic properties and DFT calculations. Dalton Trans., 2014, 43, 15359–15366.

36. Xiangyu Liu, Qi Yang, Zhiyong Su, Sanping Chen,* Gang Xie, Qing Wei, Shengli Gao. 3D high-energy-density and low sensitivity materials: synthesis, structure and physicochemical properties of an azide–Cu(II) complex with 3,5-dinitrobenzoic acid. RSC Adv., 2014, 4, 16087–16093.

37. Xiangyu Liu,  Linqiang Duan,  Qing Wei, Sanping Chen.* Two cyanide-bridged compounds composed of Schiff base–manganese(III) building block with dicyanamido and hexacyanocobaltate(III) as ligands: Crystal structure, thermostability and magnetic property. Inorg. Chim. Acta, 2014, 423, 462–468.


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